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* Bernard LAGRANGE, Biométhane 1. Une alternative crédible ; 2. principes-techniques, utilisations
* Bernard LAGRANGE, Biométhane 1. Une alternative crédible ; 2. principes-techniques, utilisations
Produces natural gas and fertilizer from our organic waste.
A biodigestor is a solution to convert organic waste into fuel gas (biogas) and fertilizer (digestate). The biodigestor particularity is that digestion is done thanks to bacterias in an environment deprived from any oxygen. This situation is called anaerobic fermentation.
Biogas is a mix of different gases, containing mainly methane, which can be used for gas cookers, boilers or as fuel for engines.
Methanogen fermentation also exists in nature. For example, it happens in swamps when organic matter is decomposed underwater.
Biogas domestication happened in the beggining of the XIXth century, and the variety of biodigestors have considerably increased since then. They are particularly present in developing tropical countries, where farmers become autonomous in energy thanks to biogas production based on organic waste. Heat being an important catalyst of this reaction, small units are economically interesting in this area.
In France and other industrialized countries, the cost of energy being very low compared to workforce cost, only few small biodigestor units exist. However, many industrial units are present in wastewater treatment plants or around big breeding farms.
Different kinds of biodigestors exist. They can be continuous or discontinuous, and also have different operation temperatures (psychrophilic : 15-25°C, mesophilic : 25-45°C or thermophilic : 45 – 65°C). In this tutorial, we are studying continuous mesophilic biodigestors at 38°C, which are the most commonly used in temperate regions.
The main feature of this system is its similarity to a digestive system, as it also needs a certain temperature to be efficient, requires bacterias and receives food regularly.
In a compost, under aerobic conditions, decomposition of organic matter produces gas (H2S, H2, NH3) and an important amount of heat. Only decomposition deprived from air produces methane. It is one of the reasons why fermentation happens in a sealed tank.
In this tutorial, we will present the different components of a biodigestor (matter circuit and gas circuit) and how to use it.
This documentation realised with the association Picojoule describes fabrication of one of their micro-methanisation protypes. It does not provide full cooking gas autonomy but is a good introduction to methanisation. Hélie Marchand's half-burried digestor has a greater capacity : Biodigesteur.
These explanations are largely inspired from the work of Bertrand Lagrange in its books Biométhane 1 and 2, that we strongly recommand !This work is free and open, do not hesitate to clarify and complete it based on your knowledge and experience.
For a good digestion at 38°C, the organic matter must remain 30 days in the biodigestor. We will size the digestor volume based on this duration and on regular inputs.
Let's take an example: if the regular input is 2L per day, as the matter must stay at least 30 days, the digestor volume must be at least 60 liters.
Degradation by the bacterias takes place in the digestor. The needed bacterias to produce methane are called methanogen bacterias. They grow in an environment deprived from oxygen, called an anaerobic environment. To remove organic matter from oxygen, it needs to be immerged into water.
Use teflon and planar joints on each side to seal the system.
The entry of the system will be the biodigestor mouth. The installation will first be done to verify dimensions of the system, and then will be dissasembled and definitively glued.
The overflow represents the end of the digestive system. Each time the system is fed, the same volume of digestate leaves the digestor. To make maintenance easier, a low exit in created. It allows draining of the digestor.
The second part will be continued vertically, until the top of the biodigestor, using 3 45° sleeves, again to prevent blockage of the system.
If the blank assembly is satisfaying, we will now glue PVC components together :
Then we will test the sealing :
This kind of biodigestor is mesophile, which means that bacterias develop between 25°C ans 45°C, ideally at 38°C. Unlike compost, biodigestion create only few heat. To reach these temperatures, heat will have to be provided to the system. It is possible to heat by different means :
It our case, given the small volume of the system, we are using a bedwarmer placed below the digestor.
To prevent the digestor from loosing energy, it is important to provide a proper isolation, so that only few heat has to be provided. In addition, a good isolation limits temperature variations, to which bacterias are very sensitive. Many differents ways exist for isolation. We chose to use corkboards, but is also possible to use straw for example, which is very cheap and provides good isolation.
We have presented the organic matter circuit, from the mouth to the digestate production. One of the main interests of th biodigestor is that it also produces methane. In this part, we will study the different components of the gas circuit, necessary to ensure a good production and purification of the fuel.
In the digestor, bacterias will produce biomethane as they degradate the organic waste. In variable proportions, it is composed of :
There can be also traces of hydrogen, oxygen, carbon monoxyde, nitrogen, and other gases in very small quantities.
Methane, CH4, belongs to the hydrocarbons family CnH2n+2, as propane (C3H8) or (C4H10). It is very light (d=0,55), and does not accumulate on the ground, unlike butane and propane, which decreases risks of explosion. Natural gas is composed mainly by methane.
To become liquid, making it easier to transport, methane has to be cooled to -165°C or compressed at a pressure of 400bars. This is only possible with industrial means, so in our case we will keep it at a gaseous state.
In terms of mass, it is the best fuel for thermic energy (12 000 Kcal/kg), but itis also the most voluminous.
Our objective is to separate methane from other gas compounds.
Its proportion depends on the bacterian reactions, the temperature and the organic waste. CO2 disturbs combustion, but does not prevent it.
The easiest is to wash the gas with water. Carbon dioxyde is very soluble (878 cm3/l at 20°C), unlike methane (34 cm3/l). This water carrying CO2 can be used for agriculture irrigation, or for algeas farming such as spirulina.
It is advisable to have a minimum of water when combustion happens, as it already produces a lot. In addition, condensation in pipes risks to block the lower parts of the gas circuit. To remove water vapour :
The bubbler reservoir can play this role of water collector if it placed at the lowest of the gas circuit.
Hydrogen sulphide (H2S) is burnable but produces sulfuric acid, which is highly corrosive. A good pH balance in the biodigestor avoids most of hydrogen sulphide production. To eliminate it, biomethane will go through iron oxide, or iron straw, that will be regenerated by exposing it to the air (sulfur will leave). Coal or clay balls can also serve as filters for hydrogen sulphide.
In the digestor, it is advised that fermentation takes place at a minimum pressure. Gas will therefore has to be evacuate along its production. Unless gas consumption is continuous and regular, it is necessary to have a storage place, supplying gas only when necessary.
Flexible reservoirs, "bladder" like, are interesting. Using a non-flexible container can be dangerous: because we will need to empty it from air befor introducing methane. Mixing air and methane can be explosive.
In any place where a flashback is feared, place a ball of iron straw or copper straw on the gas circuit. Through thermic conduction, it will decreases temperature and stifle the combustion. Be careful however not to compact too much the metallic straw in the pipes, otherwise it would impede a good circulation of gas.
In our case, to avoid flashbacks to the digestor and above all to the storage reservoir, we place iron straw in the closest pipe to the gas cooker.
As it is mixed with non combustible carbon dioxyde, biomethane has a lower calorific power than propane, butane of pure methane for the same volume.
Therefore, devices functionning with these gases have a higher air admission than a gas cooker using biomethane.
To adapt standard burners to biomethane :
CAUTION: flames from methane are less visible than from propane or butane, be careful not to get burned when using the gas cooker.
Biomethane can also be used in gas lamps, heaters, or combustion engines: generators, agricultural machines, cars...
The biodigestor and the storage are at atmospheric pressure, to ensure correct work of bacterias. The gas cooker will use 10mbar pressure. To provide this pressure:
Each connector between a component of the circuit and a gas pipe has to be securized with a hose clamp.
Once the whole circuit is assembled, test the sealing, proceeding as for the matter circuit: put the circuit under pressure and spray soapy water on each junction. If fbubbles appear, there is a leak.
The biodigestor is a living system, composed by billions of bacterias, and needs to be taken care of.
Ideally, the biodigestor has to be fed every day. It is possible to reduce it until once a week at the minimum. If the volume of organic matter is too important, it is advised to divide it in different "meals".
It is important to shred or grind the organic matter (knive, blender...) and to add their weight in water, in order to :
Biodigestor can be complementary to a compost. Indeed, compost creates humus, and needs a high carbon/nitrogen ratio (20 to 30), with mostly cellulose and lignous compounds. Too much putrescible organic matter will destructurate the compost.
Conversely, wet and putrescible matters are welcome in a biodigestor (fruits and vegetables, peelings ...) Fibrous, dry and hard matters need to be limited in the biodigestor. They may be the cause for blockage of the system, and remain in the digestor forming foam or a crust, that is difficult to remove.
High nitrogen input is ideal in the digestor, as it will stimulate bacterias activity. In addition, the digestate produced will be a rich fertilizer.
It is important to bring "green food" in the digestor diet. If peelings and leafstalks are not enough, it is possible to add grass.
Animal products (meat, milk, eggs...) should be avoided in the digestor, as it does not reaches high temperatures enough to detroy pathogens, unlike compost.
Oils have an important methanogen power (780 liters of methane per kilogram of oil!) but it brings acidity to the digestor, which might kill the bacterias when too important. Oils should be brought to the system sparingly.
Cooking water allows for system heating and fluidifies circulation. It also provides starch (potatoes, cereals, rice ...) that bacterias like.
Urine can be used in a regular basis. Feces are accepted sparingly, but they have a weak methanogen power, as an important part of their energetic value has already been absorbed during digestion.
In acid medium, the enzymatic activity of the bacterias is inhibited. This acidity is mainly due to organic acids accumulation. In basic medium, fermentation produce hydrogen sulphide (H2S) and hydrogen (H2). Digestion can take place between pH of 6,6 and 7,6, with an optimum between 7 and 7,2.
We have seen previously that feces have a weak methanogen power because they are already digested. However, they are important to launch bacterial activity in the digestor.
A cow, generates between 60 and 200 liters of biogas a day. We will recover part of its intestinal bacterias in its feces.
To launch the bacterial fermentation in the digestor:
If the activity of the biodigestor is stopped due to a long period without food, it would have to be inoculated again in the same way.
Digestion stabilisation until a regular production of biogas can last several weeks, during which it is advised not to disturb feeding.
The digestate from domestic biodigestor, one stabilized, is a liquid fertilizer rich in minerals and nitrogen.
You can dilute it at 10% in water, and use it every month for any kind of plants.
If animal products (meat, milk, eggs...) are part of the digestor diet, it is better not to use digestate for fruits and vegetables that will be eaten raw (strawberries, lettuce, carots...) It is better to used in orchards or non-food plants.
Comme tout le travail du Low-tech Lab, ce tutoriel est participatif, n'hésitez pas à ajouter les modifications qui vous semblent importantes, et à partager vos réalisations en commentaires.